SECOND-ORDER UNIMOLECULAR KINETICS IN THE THERMAL DECOMPOSITION OF HYDROGEN PEROXIDE VAPOR

نویسندگان

چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A Model for Thermal Decomposition of Hydrogen Peroxide

A one-dimensional model has been developed to investigate the thermal decomposition of rocket grade hydrogen peroxide (HP) in a stream of previously decomposed HP products. The model developed assumes steady, one-dimensional adiabatic flow and includes basic mass balances, droplet evaporation, gasphase decomposition kinetics, droplet dynamics, and control volume conservation laws. The code is a...

متن کامل

Kinetics of the decomposition of hydrogen peroxide catalyzed by ferric ethylenediaminetetraacetate complex.

Added substrates, acetone and t-butyl alcohol, strongly retard the decomposition of H(2)O(2) brought about by ferric ethylenediaminetetraacetate (EDTA) at pH 8-9.5. Their relative effectiveness and the kinetic form of the retardation are consistent with their interruption of a hydroxyl radical chain that is propagated by HO. attack both upon H(2)O(2) and on complexed and uncomplexed EDTA. Simil...

متن کامل

Hydrogen peroxide vapor is not the same as aerosolized hydrogen peroxide.

study were indistinguishable by PFGE and were isolated from the same ward (one from a patient room and the other from the men's toilet in the obstetrics and gynecology department). However, there were no reported hospital infections or outbreaks attributable to this microorganism in this ward in the 3 months before and the 3 months after the study period. During the study, it was observed that ...

متن کامل

Isothermal decomposition of hydrogen peroxide dihydrate.

We present a new method of growing pure solid hydrogen peroxide in an ultra high vacuum environment and apply it to determine thermal stability of the dihydrate compound that forms when water and hydrogen peroxide are mixed at low temperatures. Using infrared spectroscopy and thermogravimetric analysis, we quantified the isothermal decomposition of the metastable dihydrate at 151.6 K. This deco...

متن کامل

The Kinetics of the Decomposition of Peroxide by Catalase

It has been shown that the experimental results obtained by Morgulis in a study of the decomposition of hydrogen peroxide by liver catalase at 20 degrees C. and in the presence of an excess of a relatively high concentration of peroxide are quantitatively accounted for by the following mechanisms. 1. The rate of formation of oxygen is independent of the peroxide concentration provided this is g...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Canadian Journal of Chemistry

سال: 1958

ISSN: 0008-4042,1480-3291

DOI: 10.1139/v58-192